This is a preview of subscription content, log in to check access. O’Neil, M. J. Reduction of aromatic nitro compounds by titanium(III) chloride.
DOI: 10.1039/b008219h. volume 66, pages772–778(2012)Cite this article. 9536).
A detailed mechanism illustrating the reduction of a nitro to an amine using zinc (Zn). doi:10.1002/047084289X.rt181.pub2, Ullmann's Encyclopedia of Industrial Chemistry, "5-Amino-2,3-dihydro-1,4-phthalazinedione", Encyclopedia of Reagents for Organic Synthesis, Angewandte Chemie International Edition in English, "Über primäre Dinitro-, Nitronitrit- und Dialdoxim-Verbindungen der Fettreihe", https://en.wikipedia.org/w/index.php?title=Reduction_of_nitro_compounds&oldid=984463106, Articles with unsourced statements from April 2014, Creative Commons Attribution-ShareAlike License, Catalytic hydrogenation using: Raney nickel, This page was last edited on 20 October 2020, at 06:32. Tetrahedron Letters, 25, 839–842.
Zn HOAc. 659). 1 Structures Expand … 1968 Jul;24(14):5115-22. https://doi.org/10.2478/s11696-012-0195-6, DOI: https://doi.org/10.2478/s11696-012-0195-6, Over 10 million scientific documents at your fingertips, Not logged in Journal of the Chemical Society, 1945, 646–657. Use the link below to share a full-text version of this article with your friends and colleagues. Physical Data: see entries for Zinc and Acetic Acid. Amidinoanilino-1,3,5-triazines and related compounds. Chem. Pookot Sunil Kumar. , CS1 maint: multiple names: authors list (, T. V. (Babu) RajanBabu, Philip C. Bulman Page, Benjamin R. Buckley, "Tri-n-butylstannane" Encyclopedia of Reagents for Organic Synthesis 2004, John Wiley & Sons. (Ph 3 P) 3 RuCl 2 is an inexpensive catalyst, that enables a chemoselective reduction of alkyne, ketones, or nitro groups in the presence of Zn/water as a stoichiometric reductant. Whitehouse Station, NY, USA: Merck Research Laboratories. Correspondence to There is a newer version of this article, I have read and accept the Wiley Online Library Terms and Conditions of Use. Physical Data: see entries for Zinc and Acetic Acid. Lithium aluminum hydride reduces aliphatic nitro compounds to amines, but aromatic nitro compounds produce azo products. (1945). Synthesis of (3-aminophenyl) acetylene via hydrogenation of (3-nitrophenyl)acetylene over cobalt polysulfide and ruthenium sulfide catalysts.
Lyle, R. E., & Lamittina, J. L. (1974). Chemical Reviews, 102, 3667–3692. The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. Harlow, UK: Longman.
Hydrogenation of organic compounds using homogeneous catalysts. DOI:10.1021/ja01238a049. Encyclopedia of Reagents for Organic Synthesis.
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Z. Reduction of aromatic nitro compounds to amines using zinc and aqueous chelating ethers: Mild and efficient method for zinc activation. If you do not receive an email within 10 minutes, your email address may not be registered, PubMed Google Scholar.  %PDF-1.3 %���� The similar reaction of 3a or 4 led to 2α-amino-5α-cholestan-3-one (11a), that may be trapped as N-formyl derivative. CAS DOI: 10.1021/cr00066a003.
InChIKey = QTBSBXVTEAMEQO‐UHFFFAOYSA‐N, (reducing agent; causes reductive elimination of vicinal heteroatoms;2-15 cleaves heteroatom–heteroatom bonds;16-27 reduces allylic, benzylic, or α‐carbonyl‐substituted heteroatoms,28-34 activated carbonyls,35-37 and alkenes38-40). Ionic liquids-new “solutions” for transition metal catalysis. p���&�N endstream endobj 40 0 obj 89 endobj 30 0 obj << /Type /Page /Parent 26 0 R /Resources 31 0 R /Contents 36 0 R /MediaBox [ 0 0 595 842 ] /CropBox [ 0 0 595 842 ] /Rotate 0 >> endobj 31 0 obj << /ProcSet [ /PDF /Text ] /Font << /F1 33 0 R /F2 32 0 R /F3 34 0 R >> /ExtGState << /GS1 37 0 R >> /ColorSpace << /Cs6 35 0 R >> >> endobj 32 0 obj << /Type /Font /Subtype /Type1 /Encoding /WinAnsiEncoding /BaseFont /Times-Roman >> endobj 33 0 obj << /Type /Font /Subtype /Type1 /Encoding /WinAnsiEncoding /BaseFont /Times-Italic >> endobj 34 0 obj << /Type /Font /Subtype /Type1 /Encoding /WinAnsiEncoding /BaseFont /Times-Bold >> endobj 35 0 obj [ /ICCBased 38 0 R ] endobj 36 0 obj << /Length 2579 /Filter /FlateDecode >> stream Please check your email for instructions on resetting your password. Physical Data: see entries for
Whitehouse Station, NY, USA: Merck Research Laboratories.
Create . Vogel, A. I., Furniss, B. S., Hannaford, A. J., Smith, P.W.G., & Tatchel, A. R. (1989). Add / Edited: 27.05.2015 / (1944). The reduction of nitroaromatics is conducted on an industrial scale. and you may need to create a new Wiley Online Library account. Journal of Organic Chemistry, 18, 971–982. 282 Reduction of Aldehydes to Alcohols. A practical and chemoselective reduction of nitroarenes to anilines using activated iron. Bellamy, F. D., & Ou, K. (1984). DOI: 10.1016/s0040-4039(00)86770-2.
Ashley, J. N., Berg, S. S., & MacDonald, R. D. (1960).
O’Neil, M. J. 6398). Organic reaction in water.
Electrolytic reduction of organic compounds. DOI: 10.1021/jo50014a011. Johnstone, R. A. W., Willby, A. H., & Entwistle, I. D. (1985). 0000001067 00000 n DOI: 10.1039/b107270f. Nitro groups in thiophene ring systems have been transformed directly to 2012-08-08. Purification: acid washing is not uncommon, but not always vital. Part of Springer Nature. A general procedure for mild and rapid reduction of aliphatic and aromatic nitro compounds using ammonium formate as a catalytic hydrogen transfer agent. Purification: acid washing is not uncommon, but not always vital. The technique employed for nitrite determi-nation has been zinc reduction protocol (1) with some modifications. Article Purification: acid washing is not uncommon, but not always vital. InChI = 1S/Zn
Steines, S., Wasserscheid, P., & Drießen-Hölscher, B. SCHEMBL18918. InChI = 1S/Zn 0000004409 00000 n Alkyl and aryl nitro compounds behave differently. Unlimited viewing of the article/chapter PDF and any associated supplements and figures. Staiger, R. P., & Miller, E. B. The donor ether acts as a ligand and also serves as a co-solvent. (Zn) [7440‐66‐6] Zn (MW 65.39)
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